A.10gH 2的物质的量为n=
m
M =
10g
2g/mol =5mol,10gO 2的物质的量为n=
m
M =
10g
32g/mol =
5
16 mol,二者物质的量不相等,所含分子数不相等,故A错误;
B.在标准状况下,Vm=22.4L/mol,则N 2的物质的量为n=
V
Vm =
5.6L
22.4L/mol =0.25mol,CO 2的物质的量为n=
m
M =
22g
44g/mol =0.5mol,则二者的物质的量不同,即所含分子数不同,故B错误;
C.H 2O的物质的量为n=
m
M =
9g
18g/mol =0.5mol,0.5 mol Br 2,则二者的物质的量相同、分子数相同,故C正确;
D.在标准状况下,Vm=22.4L/mol,224mL=0.224L,则H 2的物质的量为n=
V
Vm =
0.224L
22.4L/mol ═0.01mol,而N 2的物质的量为0.1mol,则二者的物质的量不同,即所含分子数不同,故D错误;
故选C.