答案为生成次氯酸钠0.26mol,氢氧化钠溶液的浓度为1.3mol/L.
解析:标准状况下(0℃,1atm)
5.8L Cl2 物质的量 = 5.8L / 22.4L/mol = 29/112mol ≈0.26mol
2NaOH + Cl2 → NaCl + NaClO + H2O
2 1 1 1 1
x 29/112 y z a
解得:
x = 29/56 mol
y = z = a = 29/112mol
NaOH物质的量浓度 = 29/56mol / 0.4L = 145/112mol ≈1.3mol/L