通过前面的计算,已经知道:1、A中含NaCl0.0144mol;2、此外还含Na+0.21mol;3、不含Na2SO4.
(3)气体只能是H2S,0.04mol,所以一定含Na2S;另外一种有两种可能:Na2SO3或者Na2S2O3.
如果是Na2SO3:根据2Na2S+Na2SO3+6HCl=6NaCl+3S↓+3H2O Na2S+2HCl=2NaCl+H2S↑
则含Na2S 0.04+(0.21-0.04×2)÷2×(2/3)=0.0833 mol
Na2SO3 (0.21-0.04×2)÷2×(1/3)=0.0217 mol
如果是Na2S2O3:根据2Na2S+Na2S2O3+6HCl=6NaCl+4S↓+3H2O Na2S+2HCl=2NaCl+H2S↑
则含Na2S 0.04+(0.21-0.04×2)÷2×(2/3)=0.0833 mol
Na2S2O3 (0.21-0.04×2)÷2×(1/3)=0.0217 mol