(1)∵f(x)+2f(
1
x )=2x+
3
x (x≠0),
∴
f(x)+2f(
1
x )=2x+
3
x ,①
f(
1
x )+2f(x)=
2
x +3x,② ,
①-②×2得3f(x)=4x+
1
x ,
∴f(x)=
4
3 x+
1
3x ,x≠0.
(2)∵f(x)=
4
3 x+
1
3x ,
3xf(x)<(k+4)x 2-(k+1)x+2,k<0
∴kx 2-(k+1)x+1>0,
即(kx-1)(x-1)>0,
∵k<0,
∴x∈(
1
k ,0 )∪(0,1).