过氧化钙是一种安全无毒的物质,带有数量不等的结晶水,通常还含有部分氧化钙.

1个回答

  • (1)n(O 2)=

    0.0672ml

    22.4L/mol =0.003mol,

    2(CaO 2?xH 2O)

    .

    2CaO+O 2↑+2xH 2O

    2mol 1mol

    n(CaO 2?xH 2O)0.003mol

    n(CaO 2?xH 2O)=0.006mol,

    则n(CaO 2)=n(CaO 2?xH 2O)=0.006mol,

    故答案为:0.006mol;

    (2)n(CaCO 3)=

    0.70g

    100g/mol =0.007mol,

    ①根据Ca元素守恒,可知:n(CaO)=0.007mol-0.006mol=0.001mol,

    m(CaO)=0.001mol×56g/mol=0.056g,

    答:样品中CaO的质量为0.056g;

    ②样品中水的质量为:m(H 2O)=0.542g-m(CaO 2)-m(CaO)=0.542g-0.006mol×72g/mol-0.056g=0.054g,

    n(H 2O)=

    0.054g

    18g/mol =0.003mol,

    x=

    n (H 2 O)

    n(C aO 2 ) =

    0.003mol

    0.006mol =0.5,

    答:样品中CaO 2?xH 2O的x值为0.5.