Using the emulsification semi-continuous seeded emulsion polymerization method, a series of polymer emulsion preparation, the effects of the emulsifier types, dosage, ratio of factors on polymer emulsion and the influence of the film performance. The results show that, with the increase of the content of the emulsifier viscosity increases, the reactive anion emulsifier system of polymer emulsion viscosity ratio than reactive anion emulsifier system of low viscosity polymer emulsion; With reactive anion emulsifier, reactive anion emulsifier and the ion emulsifier blends with the preparation of polymer emulsion stability than with the reaction type anion emulsifier was of the polymer emulsion stability much; The more the contact Angle emulsifier dosage small, reaction type of anionic emulsifier polymer emulsion membrane to the contact Angle is better than the reactive emulsifiers system of the polymer emulsion membrane into the contact Angle is big; With reactive anion emulsifier made a polymer emulsion membrane water resistance than with the reaction type anion emulsifier made a polymer emulsion membrane water resistance, emulsifier dosage the worse the more water resistance, blends with system reactive emulsifiers the greater the content of water resistance, the better.
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