这是因为that you can make use of 是一个定语从句,修饰chance.所以of和后面的to虽然相邻,但其实并没有语法关系,是正确的.
把这个定语从句去掉,句子仍然成立：
This is a good chance to improve your spoken English
关于make use of,This is a good chance that you can make use of
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