(1)标准状况下放出1.12LH 2的物质的量为:
1.12L
22.4L/mol =0.05mol,则:
2Na+2H 2O=2NaOH+H 2↑
46g 1mol
m(Na)0.05mol
故m(Na)=46g×
0.05mol
1mol =2.3g
答:原混合物中金属钠的质量为2.3g;
(2)原混合物中金属钠的质量为2.3g,则m(Na 2O)=5.4g-2.3g=3.1g,
n(Na)=
2.3g
23g/mol =0.1mol,n(Na 2O)=
3.1g
62g/mol =0.05mol,
则与水反应生成的总NaOH的物质的量为:n(NaOH)=0.1mol+0.05mol×2=0.2mol,
c(NaOH)=
0.2mol
0.04L =5mol/L,
答:所得溶液的物质的量浓度为5mol/L.