论绿色化学化工及节能的基本含义?

1个回答

  • 英语原文:

    twelve principles of green chemistry:

    1.Prevent waste: Design chemical syntheses to prevent waste, leaving no waste to treat or clean up.

    2.Design safer chemicals and products: Design chemical products to be fully effective, yet have little or no toxicity.

    3.Design less hazardous chemical syntheses: Design syntheses to use and generate substances with little or no toxicity to humans and the environment.

    4.Use renewable feedstocks: Use raw materials and feedstocks that are renewable rather than depleting. Renewable feedstocks are often made from agricultural products or are the wastes of other processes; depleting feedstocks are made from fossil fuels (petroleum, natural gas, or coal) or are mined.

    5.Use catalysts, not stoichiometric reagents: Minimize waste by using catalytic reactions. Catalysts are used in small amounts and can carry out a single reaction many times. They are preferable to stoichiometric reagents, which are used in excess and work only once.

    6.Avoid chemical derivatives: Avoid using blocking or protecting groups or any temporary modifications if possible. Derivatives use additional reagents and generate waste.

    7.Maximize atom economy: Design syntheses so that the final product contains the maximum proportion of the starting materials. There should be few, if any, wasted atoms.

    8.Use safer solvents and reaction conditions: Avoid using solvents, separation agents, or other auxiliary chemicals. If these chemicals are necessary, use innocuous chemicals.

    9.Increase energy efficiency: Run chemical reactions at ambient temperature and pressure whenever possible.

    10.Design chemicals and products to degrade after use: Design chemical products to break down to innocuous substances after use so that they do not accumulate in the environment.

    11.Analyze in real time to prevent pollution: Include in-process real-time monitoring and control during syntheses to minimize or eliminate the formation of byproducts.

    12. Minimize the potential for accidents: Design chemicals and their forms (solid, liquid, or gas) to minimize the potential for chemical accidents including explosions, fires, and releases to the environment.

    要点如下:

    减少废物,原料使用更有效,设计更安全,危害小的化学路径,利用可再生原料,减少副产物,催化剂,提高能源利用率,设计可降解产品,即时监测以防止污染,减小事故发生的可能性.