1.0mol/Lde Na3PO4和2.0mol/L盐酸等体积混合,二者比例是1:2,发生反应:
Na3PO4 + 2HCl = NaH2PO4 + 2NaCl c(NaH2PO4)=1.0/2=0.5mol/L
实际上是求0.5mol/L的NaH2PO4溶液的PH值.H3PO4的PKa1=2.16,PKa2=7.21,PKa3=12.32.NaH2PO4是两性物质,其[H+]的计算简式为:
[H+]=根号下[Ka1Ka2c/(Ka1+c)]=[Ka1Ka2c/(Ka1+c)]^0.5
=[10^-2.16*10^-7.21*0.5/(10^-2.16+0.5)]^0.5=2.05*10^-5(mol/L)
所以PH=-lg[H+]=4.69