在常温下,醋酸的K为1.8×10-5,
即1.8×10-5=c(CH3COO-)c(H+)/c(CH3COOH) (1)
c(CH3COO-)+c(CH3COOH)=200mg*10(-3)/82g/mol (2)
c(H+)=10(-14)/c(OH-)
c(CH3COO-)+c(OH-)=c(Na+)+c(H+),这里c(H+)很小,略去为:
c(CH3COO-)+c(OH-)=c(Na+)
又c(CH3COO-)+c(CH3COOH)=c(Na+)
故c(OH-)=c(CH3COOH) (3)
把(2)(3)代入(1)中得:c(OH-)=c(CH3COOH) =1.17*10(-6)
pH约为8