1.2Na+2H2O→2NaOH+H2↑
Na2O+H2O→2NaOH
2Na2O2+2H2O→4NaOH+O2↑
∵放电后切好完全反应
∴n(H2):n(O2)=2:1
∴n(H2)=0.02mol,m(H2)=0.04g
n((O2)=0.01mol,m(O2)=0.32g
∴n(Na)=0.04mol,m(Na)=0.92g
n(Na2O2)=0.02mol,m(Na2O2)=1.56g
m(Na2O)=4.34-1.56-0.92=1.86g
2.溶液中m(Na2CO3)=6.36%x100=6.36g
n(Na2CO3)=0.06mol
设原混合物中NaHCO3 x mol,Na2CO3·10H2O y mol
84x+286y=11.26
x/2+y=0.06
x=0,1mol,y=0.01mol
∴m(NaHCO3)=8.4g
m(Na2CO3·10H2O)=2.86g
加热原混合物将失重11.26-6.36=4.9g