n(BaCl2)=0.05*0.1=0.005mol
n(AgNO3)=0.01*0.1=0.001mol
BaCl2 + 2AgNO3=2AgCl↓+Ba(NO3)2
0.0005```0.001`````````0.0005
所以剩余n(Ag+)=0mol c(Cl-)=0.005-0.001=0.004mol
n(Ba2+)=0.005mol n(NO3-)=0.001mol
溶液总体积0.05+0.01=0.06
c(Ag+)=0
c(Cl-)=0.004/0.06=0.0667mol/L
c(Ba2+)=0.005/0.06=0.0833mol/L
c(NO3-)=0.001/0.06=0.01667mol/L