1mol/LHCl和1mol/LNaAc等体积混合,忽略体积变化,可看成0.5mol/LNaCl和0.5mol/LHAc溶液,该溶液的pH由HAc决定,即可看成求0.5mol/L HAc溶液的pH值.
c(H+)=Ka*c(HAc)
乙酸的电离常数=1.75x10^-5
c(H+)=1.75*10^-5*0.5mol/L=8.75*10^-6
pH=-lgc(H+)=5.1
1mol/LHCl和1mol/LNaAc等体积混合,忽略体积变化,可看成0.5mol/LNaCl和0.5mol/LHAc溶液,该溶液的pH由HAc决定,即可看成求0.5mol/L HAc溶液的pH值.
c(H+)=Ka*c(HAc)
乙酸的电离常数=1.75x10^-5
c(H+)=1.75*10^-5*0.5mol/L=8.75*10^-6
pH=-lgc(H+)=5.1