(1)n(H 2)=
0.224L
22.4L/mol =0.01mol,
2Na+2H 2O=2NaOH+H 2↑
46g1mol
m(Na) 0.01mol
m(Na)=0.46g,
答:金属钠样品中含金属钠质量是0.46g;
(2)m(Na 2O)=0.77g-0.46g=0.31g,n(Na 2O)=
0.31g
62g/mol =0.005mol,混合物中n(Na)=
0.46g
23g/mol =0.02mol,
根据钠元素守恒,与水反应生成的n(NaOH)=0.02mol+0.005mol×2=0.03mol,
c(NaOH)=
0.03mol
0.1L =0.3mol/L,
答:所得溶液的溶质的物质的量浓度是0.3mol/L.