先行词是atmosphere（气氛）,是物,而定语从句又缺少主语,所以用which.先行词是人时,才能用D,who.
翻译：他有为学生营造一种良好（课堂）氛围的天赋,这种氛围能够令学生交流自如.
24.She has a gift for creating an atmosphere for her student
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