设Mg 和Al 的物质的量分别为x,y
Mg +2HCl ===MgCl2 + H2
1 22.4
x (22.4x)
2Al+6HCl ===2AlCl3 +3H2
2 3*22.4
y (1.5y*22.4)
(22.4x) + (1.5y*22.4) ==2.24 ------------(1)
2Al+ 2NaOH +2H2O == 2NaAlO2 +3H2
2 3*22.4
y (1.5y*22.4)
(1.5y*22.4) ===2.016 ------(2)
联立(1)(2)解得 x=0.01 y=0.06
质量之比为 (24*0.01):(27*0.06)=4:27