由①2Zn(s)+O 2(g)=2ZnO(s)△H 1=-702.2kJ/mol,
②2Hg(s)+O 2(g)=2Hg O(s)△H 2=-181.4kJ/mol,
根据盖斯定律可知,
①-②
2 得到Zn(s)+HgO(s)=Hg(s)+ZnO(s),
则△H 3=
-702.2kJ/mol-(-181.4kJ/mol)
2 =-260.4kJ/mol,
故选D.
由①2Zn(s)+O 2(g)=2ZnO(s)△H 1=-702.2kJ/mol,
②2Hg(s)+O 2(g)=2Hg O(s)△H 2=-181.4kJ/mol,
根据盖斯定律可知,
①-②
2 得到Zn(s)+HgO(s)=Hg(s)+ZnO(s),
则△H 3=
-702.2kJ/mol-(-181.4kJ/mol)
2 =-260.4kJ/mol,
故选D.