过滤得到的固体是Cu,m(Cu)=12.8g
Fe + 2HCl == FeCl2 + H2↑ Fe + CuCl2 == FeCl2 + Cu
56 73 2 56 135 64
m1 x 0.4g m2 y 12.8g
56/m1 = 73/x = 2/0.4
56/m2 = 135/y = 64/12.8
解得m1=11.2g,m2=11.2g,x=14.6g,y = 27g
(1)原混合物中铁粉的质量=11.2+11.2=22.4g;
(2)
CuO + 2HCl == CuCl2 + H2O
73 135
x' 27g
73/x' = 135/27
解得x' = 14.6g
所以原200克盐酸溶液中溶质的质量分数=(x+x')/200=(14.6+14.6)/200=14.6%