【解1】:
(1)化学计量点时的pH值;
[OH+] = {KwC/Kb}1/2 = {10^-14x0.050/1.8x10^-5}1/2 = 5.3x10^-6
p OH = 5.28 pH = 8.72
(2)选择酚酞指示剂 确定终点
【解2】:.已知KMnO4标准溶液的浓度为0.1810mol/L,以该溶液测定褐铁矿中的含铁量,求TFe/KMnO4 . (Ar(Fe)=55.85)
答:TFe/KMnO4 = N kmno4 x (Fe/1000) =0.1810/5 mol/Lx55.85/1000 = 0.002022 (g/ml)