(1)n(H 2)=
V ( H 2 )
V m =
1.12L
2.24L• mol -1 =0.05mol,
答:产生H 2的物质的量为0.05mol.
(2)2Na+2H 2O=2NaOH+H 2↑
46g1mol
m(Na)0.05mol
m(Na)=
46g•0.05mol
1mol =2.3g,
答:原混合物中金属钠的质量为2.3g.
(3)原混合物中金属钠的质量为2.3g,则m(Na 2O)=5.4g-2.3g=3.1g,
n(Na)=
2.3g
23g/mol =0.1mol,n(Na 2O)=
3.1g
62g/mol =0.05mol,
则与水反应生成的总NaOH的物质的量为:n(NaOH)=0.1mol+0.05mol×2=0.2mol,
c(NaOH)=
0.2mol
0.04L =5mol/L,
答:所得溶液的物质的量浓度为5mol/L.