(1)设金属钠的质量为m,根据反应的化学方程式计算,
2Na+2H 2O═2NaOH+H 2↑
2×23g2g
m0.2g
m=
2×23g×0.2g
2g =4.6g
答:未被氧的金属钠为4.6g;
(2)n(Na)=
4.6g
23g/mol 0.2mol,
固体中m(Na 20)=10.8g-4.6g=6.2g
n(Na 20)=
6.2g
62g/mol =0.1mol
由反应2Na+2H 2O═2NaOH+H 2↑,Na 2O+H 2O═2NaOH可知
溶液中溶质的物质的量为:n(NaOH)=0.2mol+2×0.1mol=0.4mol,
溶液的质量为:100g+10.8g-0.2g,
溶液的体积为:V=
m
ρ =
100g+10.8g-0.2g
1.106g/ml =100ml,即0.1L,
c=
n
V =
0.4mol
0.1L =4mol/L.
答:溶液中溶质NaOH的物质的量浓度为4mol/L.