1.
5 kg NH3 ===>5000/17 = 294.1 mol,
35 kg O2 ===>35000/32= 1094 mol
103 kg CH4 ===>103000/16=6437.5 mol
NH3 is the limiting reagent.
mass of HCN =294.1x27 =7974 g =7.974 kg
mass of H2O =294.1x6x18/2= 5081 g =5.081 kg
2.
186.207=62.60% x 186.956 + 37.40%X
find X (!),and it will be your answer.